SGS Supporting OTM-50 

The U.S. EPA’s Other Test Method (OTM)-50 establishes a consistent approach for measuring 30 volatile PFAS and other fluorinated compounds from stationary sources. These include breakdown products that can form during incomplete destruction or combustion, important indicators of how effectively PFAS treatment and destruction technologies perform. 

As the industry moves toward more rigorous evaluation of PFAS destruction technologies and their ability to mineralize PFAS, not just degrade to other potentially harmful compounds, the need for reliable air measurements is essential. OTM-50 provides a technical framework for generating actionable data, and SGS is equipped to support its full implementation. 

Until now, the industry has focused primarily on separating or sequestering PFAS on adsorptive media, but with recent advances in destructive techniques and additional research on combustion, the concern over unintended harmful by-products have also increased. That’s why OTM-50 matters: it provides an analytical framework needed to verify that destruction is complete, and to understand what’s being emitted.  

Why SGS  

As the global leader in PFAS analysis, SGS offers unmatched technical depth and analytical infrastructure to support OTM-50 projects.  

Our network provides:  

  • Certified clean canisters for accurate sampling  
  • Comprehensive logistical support for complex field deployments  
  • Validated GC-MS/MS analysis for the full OTM-50 compound list  
  • Expert interpretation and regulatory insight from our PFAS specialists  

From remediation system testing to emissions verification, SGS ensures the reliability and defensibility of your OTM-50 data.  

Find the full OTM-50 Analyte List below.  

Compound Name

CAS #

Chemical Formula

Carbon tetrafluoride  75-73-0  CF4
Hexafluoroethane (FC-116) 76-16-4 C2F6
Tetrafluoroethene 116-14-3 C2F4
Trifluoromethane (HFC-23) 75-46-7 CHF3
Octafluoropropane 76-19-7 C3F8
Difluoromethane (HFC-32) 75-10-5 CH2F2
Fluoromethane (HFC-41) 593-53-3 CH3F
Pentafluoroethane (HFC-125) 354-33-6 C2HF5
Hexafluoropropene 116-15-4 C3F6
Hexafluoropropene oxide (HFPO) 428-59-1 C3F6O
Decafluorobutane 355-25-9 C4F10
Dodecafluoropentane 678-26-2 C5F12
Tetradecafluorohexane 355-42-0 C6F14
1H-Perfluoropentane 375-61-1 C5HF11
Hexadecafluoroheptane 335-57-9 C7F16
Heptafluoropropyl-1,2,2,2-tetrafluoroethyl ether (E1) 3330-15-2 C5HF11O
1H-Perfluorohexane 355-37-3 C6HF13
1H-Perfluoroheptane 375-83-7 C7HF15
2H-Perfluoro-5-methyl-3,6-dioxanonane (E2) 3330-14-1 C8HF17O2
1H-Perfluorooctane 335-65-9 C8HF17
Octadecafluorooctane 307-34-6 C8F18
1H-Nonafluorobutane 375-17-7 C4HF9
1H-Heptafluoropropane 2252-84-8 C3HF7
1,1,1,2-Tetrafluoroethane (HFC-134a) 811-97-2 C2H2F4
Chlorodifluoromethane (HCFC-22) 75-45-6 CHClF2
Chlorotrifluoromethane (CFC-13) 75-72-9 CF3Cl
Octafluorocyclobutane (FC-C318) 115-25-3 C4F8
Octafluorocyclopentene (FC-C1418) 559-40-0 C5F8
Trichloromonofluoromethane (CFC-11) 75-69-4 CCl3F